This Standard specifies a method for the determination of high-molecular-mass cationic-active materials such as a) quaternary ammonium compounds in which two of the alkyl groups each contain 10 or more carbon atoms, e.g. distearyl-dimethyl-ammonium chlorides, or b) salts of imidazoline or 3-methylimidazolinein in which long-chain acylaminoethyl and alkyl groups are substituted in the 1- and 2-positions, respectively. The method is applicable to solids or to aqueous solutions of the active material. The relative molecular mass of the cationic-active matter shall be known or previously determined if its content is expressed as a percentage by mass. Non-ionic active agents, soap, urea and the salts of (ethylenedinitrilo) tetraacetic acid do not interfere. Typical inorganic components of detergent formulations, such as sodium chloride, sulfate, borate, tripolyphosphate, perborate, silicate, etc., do not interfere, but bleaching agents other than perborate shall be destroyed before the analysis, and the sample shall be completely soluble in water. This part of the standard should be read in conjunction with ISO 2271.